Bis(acetone 4-phenylthiosemicarbazonato-κ2 N 1,S)zinc(II)
نویسندگان
چکیده
The Zn(II) atom in the title compound, [Zn(C(10)H(12)N(3)S)(2)], is N,S-chelated by the deprotonated Schiff base in a tetra-hedral environment. The metal atom lies on a twofold rotation axis that relates one anion to the other. The amino H atom forms an intermolecular N-H⋯π inter-action to an aromatic ring.
منابع مشابه
trans-Bis[acetone (2-hydroxybenzoyl)hydrazonato-κ2 N′,O]bis(pyridine-κN)zinc(II)
In the title compound, [Zn(C(10)H(11)N(2)O(2))(2)(C(5)H(5)N)(2)], the Zn(II) atom lies on an inversion centre, and is coordinated in a distorted octa-hedral geometry by two carbonyl O atoms and two imino N atoms from two anionic bidentate acetone (2-hydroxy-benzo-yl)hydrazone ligands and by two N atoms from two pyridine mol-ecules. The hydroxyl group acts as a donor, forming an intra-molecular ...
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